Light-induced intermolecular proton transfer from gas-phase ions to neutral molecules期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Light-induced intermolecular proton transfer from gas-phase ions to neutral molecules

Institution:	1. Department of Chemistry, Indian Institute of Technology-Indore, Khandwa road, Simrol 433552, India;2. Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania 15261, United States;3. Department of Biosciences and Bio-Medical Engineering, Indian Institute of Technology-Indore, Khandwa road, Simrol 433552, India;4. Center for Electric Vehicle and Intelligent Transport Systems, Indian Institute of Technology-Indore, Khandwa road, Simrol 433552, India

Abstract:	It is shown by use of Fourier transform ion cyclotron resonance (FTICR) mass spectrometry that photoexcitation of protonated naphthalene by visible laser light of 488 nm can effect a proton transfer from this ion to acetonitrile. The reaction of the ground state reaction partners is endoergic by 31 kJ/mol.

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