Oxidation of (E,E,Z)-1,5,9-cyclododecatriene catalysed by palladium(II) acetate in the presence of copper(II) acetate and air: A kinetic study |
| |
| Affiliation: | 1. School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China;2. Xiangya School of Public Health, Central South University, Changsha 410078, China;1. Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, School of Pharmaceutical Sciences, Chongqing University, Chongqing 401331, China;2. Department of Medicinal Chemistry, School of Pharmacy, Fujian Medical University (FMU), Fuzhou 350005, China;3. Affiliated Hospital of North Sichuan Medical College and Medical Imaging Key Laboratory of Sichuan Province, Nanchong 637503, China |
| |
| Abstract: | The oxidation of (E,E,Z)-1,5,9-cyclododecatriene catalysed by Pd(OAc)2/Cu(OAc)2 was studied in methyl alcohol solutions at 2.5 MPa air pressure and temperature range of 358 to 383 K. The selectivity of ketones and ethers at conversion of cyclododecatriene up to 32.7% ranged within 87.5–96.0%. The reaction network and kinetic equations proposed suggested a significant inhibition effect of the ketones and ethers and gave the best agreement with the experimental data. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
