Adduct of Triphenylphosphine Oxide and Sulfuric Acid: Synthesis and Structure |
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| Authors: | Sharutin V. V. Egorova I. V. Ivanenko T. K. Sharutina O. K. Gerasimenko A. V. |
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| Affiliation: | (1) Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia |
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| Abstract: | Adduct of triphenylphosphine oxide and sulfuric acid was synthesized by reacting arenesulfonic acids with triphenylphosphine oxide (1 : 2) in the presence of the moisture of air. According to the X-ray diffraction data, the phosphorous atom has a distorted tetrahedral coordination. The sulfuric acid molecule is disordered over two sites and is linked with two triphenylphosphine oxide molecules through hydrogen bonds. |
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