1,4-migration of rhodium and palladium in catalytic organometallic reactions |
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Authors: | Ma Shengming Gu Zhenhua |
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Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, PR China. masm@mail.sioc.ac.cn |
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Abstract: | Mechanisms based on the 1,4-migration of metal centers have been proposed to explain some interesting transition-metal-catalyzed organic transformations. Despite the lack of solid evidence for the real nature of this process, the 1,4-metal migration reaction is proposed to proceed by the reductive elimination of trivalent intermediates for the Rh-involved reactions and of tetravalent intermediates for the Pd-catalyzed processes. These high-valent organometallic species would be formed by the oxidative addition to C-H and C-X bonds. This minireview summarizes the results in this area. |
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Keywords: | 1,4‐migration C?H activation palladium reaction mechanisms rhodium |
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