Three-component synthesis of cyclic enaminones via ketene cyclization |
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Authors: | Seki Hajime Georg Gunda I |
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Affiliation: | Department of Chemistry, Institute for Therapeutics Discovery and Development, College of Pharmacy, University of Minnesota, 717 Delaware Street SE, Minneapolis, Minnesota 55414, United States. |
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Abstract: | Cyclic six-membered enaminones were synthesized from three components (bromodiazoacetone, primary amine, and alkyne) in high yields via aza-Michael addition, Wolff rearrangement, and nucleophilic ketene cyclization. |
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