Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a Ln6Cu24Na12 cluster as a node |
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| Authors: | Zhuang Gui-Lin Chen Wen-Xian Zhao Hai-Xia Kong Xiang-Jian Long La-Sheng Huang Rong-Bin Zheng Lan-Sun |
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| Institution: | State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China. |
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| Abstract: | Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a nanosized Ln(6)Cu(24)Na(12) (Ln = Gd, Dy) cluster as a node have been obtained under microwave irradiation conditions through the reaction of H(2)ANMA (H(2)ANMA = L-alanine-N-monoacetic acid), Cu(NO(3))(2), and Ln(NO(3))(3) (Ln = Gd for 1, Dy for 2) with NaOH in deionized water. Investigations on the magnetic properties show that 1 exhibits ferrimagnetic behavior. The electrical conductivity measurements reveal that 1 behaves as a proton conductor. |
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