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Isobaric (vapour + liquid) equilibrium for (2-propanol + water + ammonium thiocyanate): Fitting the data by an empirical equation
Authors:Lutfullah M. Sevgili  Aynur Senol
Affiliation:Istanbul University, Faculty of Engineering, Department of Chemical Engineering, Avcilar, Istanbul 34320, Turkey
Abstract:Isobaric (vapour + liquid) equilibrium (VLE) data for {2-propanol (1) + water (2) + ammonium thiocyanate (3)} were obtained at 101.3 kPa experimentally. An all-glass Fischer-Labodest type still capable of handling pressures from (0.25 to 400) kPa and temperatures up to 523.15 K was used. (Vapour + liquid) equilibrium data of (2-propanol + water) were also obtained at 101.3 kPa experimentally. An equation is proposed to fit the data of salt-containing systems using dimensionless groups called relative ratio. The proposed model was also tested for the salt-containing systems given from the literature.
Keywords:Salt-effect   (Vapour     liquid) equilibrium   2-Propanol   Water
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