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芳氧端基的聚二甲基硅氧烷
引用本文:林国良 洪满水. 芳氧端基的聚二甲基硅氧烷[J]. 离子交换与吸附, 1994, 10(5): 423-427
作者姓名:林国良 洪满水
作者单位:厦门大学化学化工学院,厦门大学固体表面物理化学国家重点实验室
摘    要:通过酚类与六甲基环三硅氧烷(D3)的调聚反应,首先合成了一类含芳氧端基的聚二甲基硅氧烷(AOS).采用UV、IR、1HNMR、元素分析、分子量测定等方法,确证了所合成聚合物的结构.讨论了反应试剂摩尔比和反应条件对调聚产物分子量的影响;研究了AOS的结构与杀菌功能、絮凝作用以及水解速度的关系.

关 键 词:D_3,酚类,调聚反应,杀菌,防霉

Synthesis and Properties of Aryloxy-terminated Polydimethylsiloxanes
Hong Manshui, Lin Guoliang, Jiang Zhiyuan. Synthesis and Properties of Aryloxy-terminated Polydimethylsiloxanes[J]. Ion Exchange and Adsorption, 1994, 10(5): 423-427
Authors:Hong Manshui   Lin Guoliang   Jiang Zhiyuan
Abstract:Aryloxy-terminated polydimethylsiloxanes(AOS) were synthesized by the telomerization of hexamethylcyclotrisiloxane (D3) with phenols. The structures of AOS were characterized by UV, IR, 1HNMR and elemental analysis. Molecular weight of the polymer varies on dependence of the reaction conditions and the mole rations of the reactants was analyzed. AOS's structural influence on bactericide, flocoulation and hydrolysis were studied.
Keywords:D_3   phenol   telomerization   bactericides   mildewproof.
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