Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks |
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Authors: | Gross Adam F Sherman Elena Vajo John J |
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Affiliation: | HRL Laboratories, LLC, Malibu, CA 90265, USA. afgross@hrl.com |
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Abstract: | Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent. |
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