Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes |
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| Affiliation: | 1. INFIQC, CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, 5000 Córdoba, Argentina;2. CIQA, CONICET, Departamento de Ingeniería Química, Facultad Regional Córdoba, Universidad Tecnológica Nacional, Maestro López esq, Cruz Roja Argentina, 5016 Córdoba, Argentina;1. Institute of Solid State Physics, Bulgarian Academy of Sciences, Tzarigradsko Chaussee 72, 1784 Sofia, Bulgaria;2. D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russia;3. Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev, Build. 9, Sofia 1113, Bulgaria;1. National Demonstration Center for Experimental Engineering Training Education, Shanghai University, Shanghai 200444, China;2. Shanghai Key Laboratory of Intelligent Manufacturing and Robotics, Shanghai University, Shanghai 200072, China;1. Division of Porous Materials, UNIDEF-CONICET-CITEDEF, S.J.B. de La Salle 4397, B1603ALO Villa Martelli, Buenos Aires, Argentina;2. CONICET, Godoy Cruz 2290, C1425FQB CABA, Argentina;3. Departamento de Física Experimental, GIyA Comisión Nacional de Energía Atómica, Avda. General Paz 1499, 1650 San Martín, Buenos Aires, Argentina;4. Escuela de Ciencia y Tecnología, Universidad Nacional de San Martín, Martín de Irigoyen 3100, 1650 San Martín, Buenos Aires, Argentina;5. Laboratory for Materials Science and Technology, FRSC-UTN, Av. Inmigrantes 555, Río Gallegos 9400, Argentina;1. Department of Pharmacology and Therapeutics, Faculty of Medicine, Ebonyi State University, Abakaliki P.M.B. 053, Nigeria;2. Department of Paediatrics, Faculty of Medicine, Ebonyi State University, Abakaliki P.M.B. 053, Nigeria;3. Department of Pharmacology, College of Medical Sciences, University of Calabar, Calabar P.M.B. 1115, Nigeria;4. Department of Pharmacology and Therapeutics, College of Health Sciences, Nnamdi Azikiwe University, Awka P.M.B. 5025, Nigeria;5. Department of Physiology, College of Medicine, University of Nigeria, Enugu P.M.B. 1011, Nigeria |
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| Abstract: | [MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with CN− or L, and redox interaction between M2+ (or Cu+) and CN−, yielding elemental metal and metal carbides. |
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