The interaction of pentacarbonyl iron(O) with selected 1,2-quinone mono-oximes (2-nitrosophenols) in the presence or absence of aniline |
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| Institution: | 1. Technische Universität Dresden, Institute of Materials Science, 01069 Dresden, Germany;2. Fraunhofer-Institut für Werkstoff- und Strahltechnik, 01277 Dresden, Germany;3. Fraunhofer CCD, 1449 Engineering Research Ct, B100, 48824-1226 East Lansing, MI, USA;4. Leibniz-Institut für Polymerforschung Dresden e.V., 01069 Dresden, Germany;5. Technische Universität Dresden, Department of Chemistry and Food Chemistry, 01069 Dresden, Germany;1. Inorganic Materials and Catalysis Division, CSIR-Central Salt and Marine Chemicals Research Institute (CSIR-CSMCRI), G. B. Marg, Bhavnagar 364002, Gujarat, India;2. Computation and Simulation Unit (Analytical Discipline and Centralized Instrument Facility), CSIR-Central Salt and Marine Chemicals Research Institute (CSIR-CSMCRI), G. B. Marg, Bhavnagar 364002, Gujarat, India;3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, Uttar Pradesh, India;1. School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, Henan, PR China;2. Henan Outstanding Foreign Scientists’ Workroom, Zhengzhou 450001, Henan, PR China;1. Department of Chemical Engineering, Faculty of Engineering, Anadolu University, 26555 Eskişehir, Turkey;2. Central Research Laboratory, Bilecik Şeyh Edebali University, 11210 Bilecik, Turkey |
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| Abstract: | Reaction of pentacarbonyl iron(O) with 1,2-quinone mono-oximes (qoH) gives the Fe(qO)2 complexes as the main products together with various organic products. In the presence of aniline the main products are again the complexes Fe(qO)2 which are accompanied by the formation of organic products and complexes of type Fe(qo-A)2 where qo-A is a species arising from the coupling of the qo ligand with aniline. The formation of the latter type of complex and of the organic products is rationalized in terms of deoxygenation of the qo ligand. The complexes Fe(qo)2 and Fe(qo-A)2 have oligomeric structures as indicated by their magnetic properties and Mössbauer spectra. Both these types of complex react with pyridine to give dipyridine adducts. |
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