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The structure of the mixed-valence,chloro-bridged dimeric complex cation [Ru2(NH3)6Cl3]2+
Affiliation:1. Departments of Chemistry, King''s College, Campden Hill Road, London W8 7AH, U.K.;2. Departments of Microbioloy, King''s College, Campden Hill Road, London W8 7AH, U.K.;1. Semiconductor Materials and Device Laboratory, Department of Semiconductor Science, Dongguk University-Seoul, Seoul 04623, Korea;2. Department of Chemistry, Indian Institute of Technology, Ropar, Panjab 140001, India;1. Department of Chemistry, Villanova University, 800 Lancaster Ave., Villanova, PA 19085, United States;2. Math, Science and Technology Department, University of Minnesota, Crookston, 2900 University Ave., Crookston, MN 56716, United States;1. Univ Lyon, INSA-Lyon, CNRS, UCBL, MATEIS, UMR 5510, 7 Avenue Jean Capelle, F-69621, Villeurbanne, France;2. Univ Lyon, INSA-Lyon, CNRS, UCBL, MATEB, 7 Avenue Jean Capelle, F-69621, Villeurbanne, France;3. EDF R&D, Les Renardières, F-77250, Moret sur Loing, France
Abstract:The cation in the ruthenium blue [Ru2(NH3)6Cl3](BPh4)2 is a trichloro-bridged bioctahedral dimer, with a RuRu distance of 2.753 Å.
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