Reactions of the metal-metal triple bond in Cp2Mo2(CO)4 and related complexes |
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| Affiliation: | 1. Department of Chemistry, CICECO – Aveiro Institute of Materials, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, Portugal;2. REQUIMTE/LAQV & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal;3. Galp Energia, Refinaria de Matosinhos, 4452-852 Leça da Palmeira, Matosinhos, Portugal;1. Department of Chemistry, University of Reading, Whiteknights, Reading, Berkshire, RG6 6AD, UK;2. Centre for Sustainable Chemical Technologies, 1 South, 1.05, University of Bath, Bath, BA2 7AY, UK |
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| Abstract: | The reactions of the MM triple bonds in compounds of type Cp2M2(CO)4 (M = Cr, Mo or W) are reviewed. These reactions are grouped under the headings of synthesis and structures of Cp2M2(CO)4-type compounds, nucleophilic additions to the MM bonds, reactions with 1,3-dipoles, oxidative reactions with nonmetals, and cluster-building reactions. Literature coverage is until the end of 1985 with 102 references. |
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