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Synthesis and characterization of dichlorodicarbonylruthenium(II) complexes of oxygen,sulphur and nitrogen donor ligands
Affiliation:1. School of Mathematics and Physics, Lanzhou Jiaotong University, Lanzhou 730070, China;2. School of Mechanical Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China;1. Medical College of Dalian University, Dalian, Liaoning Province 116622, China;2. Key Laboratory of Natural Resources and Functional Molecules of the Changbai Mountain, Affiliated Ministry of Education, Yanbian University College of Pharmacy, Yanji, Jilin Province 133002, China
Abstract:Complexes of dichlorodicarbonylruthenium(II) of formula [RuCl2(CO)2L2] (L = tetramethylthiourea, monomethylthiourea, dimethylthiourea, pyridine 2-thiol, piperidine or pyridine) and [RuCl2(CO)2L′ (L′= 1,2-diaminoethane or tetramethylurea), have been prepared. The complexes were characterized by their IR, NMR and elemental analyses.
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