Influence of the structure of alkyl derivatives of salicylaldehyde oxime upon the extraction rate of copper from diluted acidic solutions |
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| Affiliation: | 1. Department of Chemistry, College of Science, Al-Hussein Bin Talal University, Ma''an, Jordan;2. Department of Clinical Laboratory Sciences, School of Science, The University of Jordan, Amman 11942, Jordan;3. Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, Chemnitz D-09107, Germany |
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| Abstract: | Individual pure alkyl derivatives of salicylaldehyde oxime were used for copper extraction using the short-time phase contacting method. The influence of the oxime structure upon the extraction rate and the surface activity was discussed. It was found that the reaction can proceed at the interface and in the bulk of the aqueous phase. The bulk-phase process is dominant for oximes having less than four carbon atoms in the alkyl group, while the interfacial process is dominant for oximes having more than six carbon atoms. |
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