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Angular overlap parameters for ruthenium(II) complexes

Institution:	1. School of Science, Sanjeev Agrawal Global Educational (SAGE) University, Bhopal 462 022, India;2. Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhopal 462 066, India;1. School of Science, SAGE University Bhopal, Bhopal 462 022, India;2. Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhopal 462 066, India;1. Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhopal 462 066, India;2. School of Science, SAGE University Bhopal, Bhopal 462 022, India

Abstract:	Approximate Angular Overlap Model e_π parameters have been obtained for a number of ligands L by comparison of the t_2g(Ru) → π^*(bpy) transition energies in Ru(bpy)₂L₂] complexes. The filled t_2g subshell of Ru(II) limits the effects of otherwise strongly π-donating ligands.

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