Synthesis and x-ray crystal structure of [{(C5H4Me)Fe(CO)2}2BiCl]3: A compound containing a planar six-membered Bi3Cl3 ring |
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| Institution: | 1. Department of Chemistry, Shivaji University, Kolhapur, MH 416 004, India;2. Technical Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India;3. Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India;1. Institute of Photonic Technologies (LPT), Friedrich-Alexander-Universität Erlangen-Nürnberg, Konrad-Zuse-Straße 3-5, 91052 Erlangen, Germany;2. Polymer Optical Fiber Application Center, Technische Hochschule Nürnberg, Wassertorstraße 10, 90489 Nürnberg, Germany;3. fiveTAU, Ing.- Gesellschaft für innovative Systeme, Römerhofweg 11, 85748 Garching, Germany;4. Bayerisches Laserzentrum GmbH (blz), Konrad-Zuse-Straße 2-6, 91052 Erlangen, Germany;5. Erlangen Graduate School in Advanced Optical Technologies (SAOT), Paul Gordan Straße 6, 91052 Erlangen, Germany |
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| Abstract: | The reaction between BiCl3 and two equivalents of Na(C5H4Me)Fe(CO)2] affords the title complex, {(C5H4Me)Fe(CO)2}2BiCl]3, containing a planar six-membered Bi3Cl3 ring in which each bismuth is bonded to two chlorine atoms and two (C5H4Me) Fe(CO)2 fragments. |
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