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Stereoselective electrochemical transformation of 4-substituted cyclohexanones into cis-5-substituted 2,2-dimethoxycyclohexanols |
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| Authors: | Elinson M. N. Feducovich S. K. Dmitriev D. E. Dorofeev A. S. Vereshchagin A. N. Nikishin G. I. |
| Affiliation: | (1) Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
| Abstract: | Electrolysis of 4-substituted cyclohexanones in methanol in the presence of sodium halides as mediators in an undivided cell results in the stereoselective formation of cis-5-substituted 2,2-dimethoxycyclohexanols in 70—80% yields. |
| Keywords: | electrolysis electrochemical oxidation stereoselectivity substituted cyclohexanones mediators 5-substituted 2,2-dimethoxycyclohexanols |
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