| Structural Studies of [V_2S_6O_2(CuPPh_3)_4(CuMeCN)_2]·2CH_2Cl_2·2PrOH |
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| 引用本文： | ZHANG Han-Hui,YU Xiu-Fen,YANG Rong-Sheng,ZHENG Fa-Kun,HUANG Liao-Yuan,ZHUO Ru-Peng(Department of Chemistry,Fuzhou University,Fuzhou,Fujian,350002)(State Key Laboratory of Structural Chemistry,Fuzhou,Fujian,350002). Structural Studies of [V_2S_6O_2(CuPPh_3)_4(CuMeCN)_2]·2CH_2Cl_2·2PrOH[J]. 结构化学, 1996, 0(5) |
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| 作者姓名： | ZHANG Han-Hui YU Xiu-Fen YANG Rong-Sheng ZHENG Fa-Kun HUANG Liao-Yuan ZHUO Ru-Peng(Department of Chemistry Fuzhou University Fuzhou Fujian 350002)(State Key Laboratory of Structural Chemistry Fuzhou Fujian 350002) |
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| 作者单位： | ZHANG Han-Hui;YU Xiu-Fen;YANG Rong-Sheng;ZHENG Fa-Kun;HUANG Liao-Yuan;ZHUO Ru-Peng(Department of Chemistry，Fuzhou University，Fuzhou，Fujian，350002)(State Key Laboratory of Structural Chemistry，Fuzhou，Fujian，350002) |
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| 摘 要： | ＳｔｒｕｃｔｕｒａｌＳｔｕｄｉｅｓｏｆ［Ｖ_２Ｓ_６Ｏ_２（ＣｕＰＰｈ_３）_４（ＣｕＭｅＣＮ）_２］·２ＣＨ_２Ｃｌ_２·２ＰｒＯＨＺＨＡＮＧＨａｎ－Ｈｕｉ；ＹＵＸｉｕ－Ｆｅｎ；ＹＡＮＧＲｏｎｇ－Ｓｈｅｎｇ；ＺＨＥＮＧＦａ－Ｋｕｎ；ＨＵＡＮＧＬｉａｏ－Ｙｕ...
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Structural Studies of [V_2S_6O_2(CuPPh_3)_4(CuMeCN)_2]·2CH_2Cl_2·2PrOH |
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| ZHANG Han-Hui,YU Xiu-Fen,YANG Rong-Sheng,ZHENG Fa-Kun,HUANG Liao-Yuan,ZHUO Ru-Peng. Structural Studies of [V_2S_6O_2(CuPPh_3)_4(CuMeCN)_2]·2CH_2Cl_2·2PrOH[J]. Chinese Journal of Structural Chemistry, 1996, 0(5) |
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| Authors: | ZHANG Han-Hui YU Xiu-Fen YANG Rong-Sheng ZHENG Fa-Kun HUANG Liao-Yuan ZHUO Ru-Peng |
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| Abstract: | The title V-Cu-S heterometallic cluster compound C84 H86Cl4Cu6N2O4P4S6V2, crystallizes in the monoclinic space group P21/n with a=16.381(5), b=17.114(3),c=16.749(6) A,β=107. 04(3)°,V=4490(2)A3, Mr=2128.84,Z=2,Dc=1. 57 g/cm3,μ= 19. 6 cm-1,F(000)=2160. Final R=0.074(Rw=0.082) for 2662 unique reflections with I≥3σ(I). The V atom in the compound retains the tetrahedral geometry of the VS3O with S-V-S or S-V-O angles of 108.6(6)～110.3 (6)°.The cluster core [V2Cu6S6O2] of the compound can be regarded as two cluster cores [VCu3S3O] bonded by bondings of the Cu-Cu'(distances of 2.774(3)～2.707(5) A) and Cu-S (distances of 2.463(7)～2.396(9) A) with centrosymmetric. Atoms of the cluster core V2Cu6 form a distorted cube with the Cu Cu'or the V-Cu distances of 2. 774(3)～2. 707(5) A. |
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| Keywords: | crystal structure vanadium cluster copper cluster |
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