Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
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| Authors: | Ibrahim Saad Woi Pei Meng Alias Yatimah Pickett Christopher J |
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| Affiliation: | Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich, UK NR4 7TJ. |
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| Abstract: | We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix. |
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