|
|||||
|
|
On the nature of the transition metal-main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes |
|
| Authors: | Durango-García Clara J Jiménez-Halla J Oscar C López-Cardoso Marcela Montiel-Palma Virginia Muñoz-Hernández Miguel A Merino Gabriel |
| Affiliation: | Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001 Col. Chamilpa, Cuernavaca, Morelos, México. |
| Abstract: | The iridum-gallyl complex MeIr(PCy(3))(2)(GaMe(2))(Cl*GaMe(3)) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) ?. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a π orbital contribution. |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ | |