| 聚合物固载的聚乙二醇季铵盐型相转移催化剂的合成、表征及相转移催化作用 |
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| 引用本文： | 冯鸣华,赵力,梁逊.聚合物固载的聚乙二醇季铵盐型相转移催化剂的合成、表征及相转移催化作用[J].离子交换与吸附,1996(3). |
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| 作者姓名： | 冯鸣华 赵力 梁逊 |
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| 作者单位： | 南开大学化学系 |
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| 摘 要： | 合成了一系列含有聚乙二醇链和季铵盐两种活性中心的高分子相转移催化剂，并考察了它们在正溴辛烷与固体碘化钠的亲核取代反应中的相转移催化性能。结果表明，催化反应对ｎ—Ｃ８Ｈ１７Ｂｒ浓度为表观一级。温度、溶剂和微量水等反应条件对催化反应有较大影响，从反应动力学、本征反应性和内扩散等方面讨论了实验结果。
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| 关 键 词： | 聚合物固载化，相转移催化，三相催化 |
SYNTHESIS,CHARACTERIZATION AND PHASE-TRANSFER CATALYSIS OF POLYMER-SUPPORTED POLYETHYLENE GLYCOL AND ONIUM PHASE-TRANSFER CATALYST |
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| Feng Minghua, Zhao Li, Liang Xun.SYNTHESIS,CHARACTERIZATION AND PHASE-TRANSFER CATALYSIS OF POLYMER-SUPPORTED POLYETHYLENE GLYCOL AND ONIUM PHASE-TRANSFER CATALYST[J].Ion Exchange and Adsorption,1996(3). |
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| Authors: | Feng Minghua Zhao Li Liang Xun |
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| Abstract: | A series of polymer- supported polyethylene glycol phase transfer catalysts with multiple active centers were immobilized by quaterisation of PEG tertiary amine with Chloromethylated copolymer (St-DVB). The kinetic reaction of 1 -bromooctane and solid sodium iodide catalyzed by this catalyst was investigated.The results showed the catalytic activity of this catalyst with PEG and onium as active centers was increased. |
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| Keywords: | Polymer-supported Phase - transfer catalysis Triphase catalysis |
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