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Photoinduced macroscopic chiral structures in a series of azobenzene copolyesters
Authors:L Nedelchev  L Nikolova  A Matharu  PS Ramanujam
Institution:(1) Optilink A/S, Frederiksborgvej 399, DK-4000 Roskilde, Denmark, DK;(2) Central Laboratory of Optical Storage and Processing of Information, Bulgarian Academy of Sciences, Sofia 1113, Bulgaria, BG;(3) Optics and Fluid Dynamics Department, Riso National Laboratory, DK-4000 Roskilde, Denmark, DK
Abstract:A study of the propagation of elliptically polarized light and the resulting formation of macroscopic chiral structures in a series of azobenzene side-chain copolyesters, in which the morphology is varied from liquid crystalline to amorphous, is reported. Real-time measurements are presented, showing the dynamic behavior of the photoinduced rotation of the polarization ellipse in the different samples. The relationship between the ellipticity of the recording light and the linear birefringence induced is studied. A numerical solution that takes into account the influence of the photoinduced linear dichroism on the light propagation through the samples is presented. Received: 10 June 2002 / Revised version: 26 July 2002 / Published online: 15 November 2002 RID="*" ID="*"Corresponding author. Fax: +45-4677/4588, E-mail: lian.nedelchev@risoe.dk RID="**" ID="**"Permanent address: Department of Chemistry and Physics, The Nottingham Trent Unversity, Clifton Lane, Nottingham NG11 8NS, England
Keywords:PACS: 42  25  Lc  42  70  -a  78  20  -e
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