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Steroidal polyols from Far-Eastern starfishes Henricia sanguinolenta and H. leviuscula leviuscula
Authors:E V Levina  A I Kalinovskii  V A Stonik  P S Dmitrenok
Institution:(1) Pacific Institute of Bioorganic Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation
Abstract:Two new compounds were isolated from two Far-Eastern starfish species, Henricia sanguinolenta and H. leviuscula leviuscula, collected in the Sea of Okhotsk, viz., the glycoside sanguinoside C, (20R,22E,24R,25S)-3-O-(2,3,4-tri-O-methyl-beta-xylopyranosyl)-24-methyl-5agr-cholest-22-ene-3beta,4beta,6beta,8beta,15agr,26-hexol, and a steroidal ketone, (20R,24S)-3beta,6beta,24-trihydroxy-5agr-cholestan-15-one. They exhibit moderate cytostatic activity with respect to the eggs of sea urchin Strongylocentrotus intermedius.
Keywords:starfish  Henricia sanguinolenta  H  l  leviuscula  polyhydroxysteroids  glycosides  aglycons  1H and 13C NMR spectra
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