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S-matrix study on alignment dependence of single ionization of molecular ions with different active orbitals
Authors:Li Yan  Jia Xin-Yan  Yang Shi-Ping  Li Wei-Dong  Chen Jing
Affiliation:Department of Physics, Hebei Normal University, Shijiazhuang 050016, China; Institute of Applied Physics and Computational Mathematics, P. O. Box 8009, Beijing 100088, China; Institute of Theoretical Physics and Department of Physics, Shanxi University, Taiyuan 030006, China; Center for Applied Physics and Technology, Peking University, Beijing 100871, China
Abstract:The orientation-dependent single ionization rate of the diatomicmolecular ion H$_2^+$ with different active orbitals in an intensefield is studied by using S-matrix theory. Our results show thatthe orientation-dependent single ionization probability of H$_2^+$is greatly dependent on the symmetry and the electron densitydistribution of its initial states, and it can be used to identifythe excited state of the molecular ion in the dissociation process.
Keywords:alignment molecule   ionization probability   molecularorbits
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