| Cu[C5H3N(CCH3=N-C6H5)2]2(PF6)2配合物的合成、晶体结构和热分解反应动力学 |
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| 引用本文： | 蒋毅民,谭黎峰,银秀菊,钟新仙,张淑华.Cu[C5H3N(CCH3=N-C6H5)2]2(PF6)2配合物的合成、晶体结构和热分解反应动力学[J].无机化学学报,2002,18(8):802-806. |
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| 作者姓名： | 蒋毅民 谭黎峰 银秀菊 钟新仙 张淑华 |
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| 作者单位： | 1. 广西师范大学化学化工系,桂林,541004
2. 桂林医学院药学系,桂林,541004 |
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| 摘 要： | The title complex CuC5H3N(CCH3=N-C6H5)2]2(PF6)2 has been synthesized by reaction of Schiff base C5H3N(CCH3=N-C6H5)2 and cupric sulfate in toluene solution. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 1041.85. The crystal structure belongs to triclinic system with space group P1 and cell parameters: a=12.6470(10)?, b=14.123(2)?, c=15.613(2)?;α=66.150(10)°,β=79.470(10)°,γ=78.290(10)°, V=2481.6(5)?3, Z=2, Dc=1.394Mg·m-3 and F(000)=1064. The final RI >2σ(I)]:R1=0.0668, wR2=0.1927; R(all data): R1=0.1133, wR2=0.2357. The Cu(Ⅱ) was coordinated by six nitrogen, at the same time the Cu(Ⅱ) formed a distorted octahedron, besides the angles and planes of this compound were discussed . The result of kinetics of the thermal decomposition indicated that the first step of it is 2 series chemical reactions, the function of machanism is f(a)=(1-a)2, and the activation energy is 144.64E/kJ. CCDC: 180872.
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| 关 键 词： | 铜配合物 Schiff碱 晶体结构 |
| 修稿时间： | 2002年3月1日 |
Synthesis and Crystal Structure of Complex Cu[C5H3N(CCH3=N-C6H5)2]2(PF6)2 and its Kinetics of Thermal Decomposition |
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| JIANG Yi-Min,TAN Li-Feng,YIN Xiu-Ju,ZHONG Xing-Xian and ZHANG Shu-Hua.Synthesis and Crystal Structure of Complex Cu[C5H3N(CCH3=N-C6H5)2]2(PF6)2 and its Kinetics of Thermal Decomposition[J].Chinese Journal of Inorganic Chemistry,2002,18(8):802-806. |
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| Authors: | JIANG Yi-Min TAN Li-Feng YIN Xiu-Ju ZHONG Xing-Xian and ZHANG Shu-Hua |
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| Institution: | Department of Chemistry,Guangxi Normal University, Guilin 541004,Department of Pharmacy,Guilin Medicine Institute, Guilin 541004,Department of Chemistry,Guangxi Normal University, Guilin 541004,Department of Chemistry,Guangxi Normal University, Guilin 541004 and Department of Chemistry,Guangxi Normal University, Guilin 541004 |
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| Abstract: | |
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| Keywords: | Schiff base copper complex crystal structure kinetics of thermal decomposition |
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