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Palladium(0)‐Catalyzed Intermolecular Arylative Dearomatization of β‐Naphthols |
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| Authors: | Ren‐Qi Xu Ping Yang Hang‐Fei Tu Shou‐Guo Wang Prof?Dr Shu‐Li You |
| Institution: | 1. http://shuliyou.sioc.ac.cn/;2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China |
| Abstract: | The first Pd0‐catalyzed intermolecular arylative dearomatization of β‐naphthols with aryl halides is described. It was found that Q‐Phos could facilitate the palladium‐catalyzed cross‐coupling‐type dearomatization of β‐naphthols, while avoiding O‐arylation, to construct 2‐naphthalenones in excellent yields and with high chemoselectivity. |
| Keywords: | cross-coupling dearomatization homogeneous catalysis naphthol palladium |