Oxidation State Dependent Coordination Modes: Accessing an Amidate‐Supported Nickel(I) δ‐bis(C−H) Agostic Complex期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Oxidation State Dependent Coordination Modes: Accessing an Amidate‐Supported Nickel(I) δ‐bis(C−H) Agostic Complex

Authors:	D Dawson Beattie Eric G Bowes Marcus W Drover Prof Dr Jennifer A Love Prof Dr Laurel L Schafer

Institution:	Department of Chemistry, The University of British Columbia, Vancouver, BC, Canada

Abstract:	Amidate‐supported two‐ and three‐coordinate Ni^I complexes were synthesized by reduction of the corresponding Ni^II precursors. A dramatic change in binding mode is observed upon reduction from Ni^II to Ni^I. The Ni^I derivatives include an unprecedented Ni^I bis(C?H) agostic complex and a two‐coordinate Ni^I complex.

Keywords:	agostic complexes AIM calculations amidate nickel redox states