Copper Salt‐Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2 with α‐Diazocarbonyl Derivatives

Herein, we report a copper salt‐controlled divergent reactivity toward α‐diazocarbonyl compounds. By a simple change of the copper counteranion under identical reaction conditions, the reported method allowed an easy access to either (Z)‐α‐fluorovinylphosphonate or alkyl‐SCF₂PO(OEt)₂ derivatives in good yields. Mechanistic studies were performed and suggested two different pathways to explain the formation of these products.