Mechanism of the Reaction of 1,1-Dimethylhydrazine with Copper(II) and Palladium(II) Chloride Complexes Containing Poly-(N-2-Alcoxycarbonylethyl)-Ethyleneimine期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Mechanism of the Reaction of 1,1-Dimethylhydrazine with Copper(II) and Palladium(II) Chloride Complexes Containing Poly-(N-2-Alcoxycarbonylethyl)-Ethyleneimine

Authors:	I. S. Kalashnikova T. L. Lebedeva A. A. Grechnikov N. A. Plate B. F. Myasoedov

Affiliation:	(1) Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 117912, Russia;(2) Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 117975, Russia

Abstract:	The mechanism of the sorption of 1,1-dimethylhydrazine vapors with metal chloride complexes of poly-(N-2-R-oxycarbonylethyl)-ethyleneimines (R = –n-C₄H₉, –n-C₁₀H₂₁) was studied by Fourier transform IR spectroscopy (FTIR) and piezoelectric resonance. The structure of the products was determined. This allowed for the optimization of the chemical composition and structure of poly-(N-2-R-oxycarbonylethyl)-ethyleneimine-based complexes in their use as sensitive coatings of piezoelectric sensors for determining 1,1-dimethylhydrazine vapors in air.

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