Supramolecular chelate copper(II) complex with 4-[(ethoxyimino)(phenyl)methyl]-5-methyl-2-phenyl-1Hpyrazol-3(2H)-one: Synthesis, crystal structure, and properties |
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Authors: | W -K Dong G Wanga Y -X Sun X -Y Dong J Yao X -H Gaob |
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Institution: | 1820. Lanzhou Jiaotong University, West Anning Road 88, Lanzhou, 730070, P. R. China 2820. Lanzhou Petrochemical Research Center, PetroChina, Lanzhou, P. R. China
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Abstract: | A supramolecular Cu(II) complex, Cu(L)2(H2O)]·C2H5OH {HL = 4-(ethoxyimino)(phenyl)methyl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one]} was synthesized and characterized structurally. The structure of the Cu(II) complex consists of one Cu(II) atom, two bidentate L-units, one coordinated H2O and one crystallization ethanol molecule. The Cu(II) atom of the complex has a slightly distorted tetragonal pyramidal geometry. Moreover, every Cu(II) complex molecule links four other molecules into an infinite 2D-layer supramolecular structure via intermolecular O-H…O, O-H…N, and C-H…O hydrogen bonds. |
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