Quinine/selectfluor combination induced asymmetric semipinacol rearrangement of allylic alcohols: an effective and enantioselective approach to alpha-quaternary beta-fluoro aldehydes |
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| Authors: | Wang Min Wang Bao Min Shi Lei Tu Yong Qiang Fan Chun-An Wang Shao Hua Hu Xiang Dong Zhang Shu Yu |
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| Affiliation: | State Key Laboratory of Applied Organic Chemistry & Department of Chemistry, Lanzhou University, Lanzhou, 730000, P. R. China. |
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| Abstract: | A quinine/Selectfluor combination inducing rearrangement reaction of allylic alcohols was discovered, which involved a moderate yield with good enantioselective construction of alpha-quaternary carbon center and beta-fluoro aldehyde under base condition. |
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