Heterogeneous phase transfer catalysts 1. Synthesis and catalytic properties of polymeric crown-ethers on inorganic supports |
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Authors: | Loktev V. F. Morozova I. Yu. Tashmukhamedova A. K. Likholobov V. A. |
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Affiliation: | (1) Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk;(2) Tashkent State University, USSR |
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Abstract: | A number of new heterogeneous phase transfer catalysts based on polymeric dibenzo-crown-ethers supported on the carbonaceous material Sibunite, ultrafine diamonds, or silica gel are synthesized. The activity of several of the catalysts for the reaction of 1-bromooctane with KI is higher than that of previously known analogs. The catalytic effect depends on the support, linker, and solvent.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1257–1262. June. 1990. |
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