Chemistry of chromium bis-acetylide complexes |
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| Authors: | A López-Hernández K Venkatesan H W Schmalle and Heinz Berke |
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| Institution: | (1) Institute of Inorganic Chemistry, University of Z?rich, Winterthurerstrasse 190, 8057 Z?rich, Switzerland; |
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| Abstract: | Abstract Stable paramagnetic Cr(II) and Cr(III) bis(alkynyl) complexes of the type trans(RC≡C)2Cr(dmpe)2]
n+ (R = Ph, SiMe3, SiEt3, C≡C–SiMe3
n = 0, 1) were prepared and characterised by NMR, cyclic voltammetry, EPR, magnetic measurements, and X-ray single-crystal
diffraction studies. |
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