| Synthesis of New Cyclic Phosphate of Arylglyoxylonitrile Oximeand Their Diastereomers |
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| 作者姓名： | Zhi Hua MA Rut Lian SHAO Hong Min MA Jun Ran CHENG Run Qiu HUANG |
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| 摘 要： | Aspartofourinterestintheemergenceofnewcompoundsinthetieldofagrocllemicalsmanut'acttlring.wehavesynthesizedaseriesofstructurallyrelatedcompoundsbelongingtothet\\'Ofollowingfamiliesf1.3.2-dioxaphosphorinane-2-oneandoximeester'.Thec}'clicphosphateintroducedinourtargetmoleculecouldserveasbothanewcarrierandanactivepal-tofthemolecule.trails-2-chloro-2-oxo-4-phenyl-51.3.2-dioxaphosphorinaneI).,II7s-liseasily'obtainedbyrefluxinga1llixtureofl,3-propandiolsandPOCI;illdichloromethene--.Thereactionofir…
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Synthesis of New Cyclic Phosphate of Arylglyoxylonitrile Oxime and Their Diastereomers |
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| Zhi Hua MA, Rut Lian SHAO, Hong Min MA, Jun Ran CHENG, Run Qiu HUANG.Synthesis of New Cyclic Phosphate of Arylglyoxylonitrile Oximeand Their Diastereomers[J].Chinese Chemical Letters,1999(6). |
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| Authors: | Zhi Hua MA Rut Lian SHAO Hong Min MA Jun Ran CHENG Run Qiu HUANG |
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| Institution: | National Key Laboratory of Elemento -Organic chemistry Nankai University. Tianjin 300071 |
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| Abstract: | Keeping in view the biological activitics of 1.3.2-dioxaphosphorinane-2-one and oximeesters. some compounds possessing these two moieties have been synthesized. Theconfigurational assignment and the ratio of ets irans diasteromers of target produets wereperformed on basis of 1H NMR. 31P NMR and confirmed by X-ray diffraction analysis. |
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| Keywords: | 1 3 2-Dioxaphosphorinane-2-one arylglyoxylonitrile diastereomers |
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