| Synthesis and Crystal Structure of [Cu (C_8H_4O_2F_3S) (2, 2' -bipy) ] |
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| 引用本文： | WANG Dong-Mei, XUE Bao-Yu, YANG Rui-Na, JIN Dou-Man(Henan Institute of Chemistry,Zhengzhou 450003)CHEN Liao-Rong ,LUO Bao-Sheng(Wuhan University,Wuhan 430072). Synthesis and Crystal Structure of [Cu (C_8H_4O_2F_3S) (2, 2' -bipy) ][J]. 结构化学, 1997, 0(4) |
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| 作者姓名： | WANG Dong-Mei XUE Bao-Yu YANG Rui-Na JIN Dou-Man(Henan Institute of Chemistry Zhengzhou 450003)CHEN Liao-Rong LUO Bao-Sheng(Wuhan University Wuhan 430072) |
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| 作者单位： | WANG Dong-Mei; XUE Bao-Yu; YANG Rui-Na; JIN Dou-Man(Henan Institute of Chemistry，Zhengzhou 450003)CHEN Liao-Rong ;LUO Bao-Sheng(Wuhan University，Wuhan 430072) |
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| 摘 要： | 1INTRODUCTIONCoppercomplexesarewidelyusedascatalystsinthedecompositionofdisubsti-tutedperoxides"'-Theelectronicstructureandbondingatthecatalystscanbeprof-itablypursuedbystudyingmodelcomplexes.Generally,theCu(I)complexesareob-tainedbyreactionofCu(l)saltswithligands.Wereporthereamethodofpreparingcopper(I)complexbythereactionofCupowderwith2-thenoyltrifluoroacetone,2,2'-bipyinmethanol.2EXPERIMENTALReactionwascarriedoutundernitrogenatmosphere.2,2-bipy(1mmol)wasaddedtoamixtureof2-thenoyl…
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| 关 键 词： | copper(Ⅰ) complex crystal structure synthesis |
Synthesis and Crystal Structure of [Cu (C_8H_4O_2F_3S) (2, 2' -bipy) ] |
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| WANG Dong-Mei, XUE Bao-Yu, YANG Rui-Na, JIN Dou-Man. Synthesis and Crystal Structure of [Cu (C_8H_4O_2F_3S) (2, 2' -bipy) ][J]. Chinese Journal of Structural Chemistry, 1997, 0(4) |
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| Authors: | WANG Dong-Mei XUE Bao-Yu YANG Rui-Na JIN Dou-Man |
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| Abstract: | Reaction of Cu powder with 2-thenoyltrifluoroacetone and 2, 2-bipygave a complex [Cu(C8H4SO2F3) (2, 2' -bipy)]. The title compound is monoclinic sys-tem, sapce grop C2/c, a= 17. 892(5), b= 18. 495(4), c= 16. 242(6) A, β=121. 02(2)°, Z=8, V=4606. 2 A3, Dc= 1. 512 g/cm3, μ= 12. 724 cm-1, F(000) = 1766,Mr = 440. 6, Final R = 0. 061 and R. = 0. 071. X-ray crystal structure analysis revealedthat copper(I) is coordinated by two O and two N atoms. The Cu(I) atom displays anearly square planar coordination geometry. |
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| Keywords: | copper(Ⅰ) complex crystal structure synthesis |
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