An approach to the synthesis of tricholomalide A: an effective means for achieving homo-Robinson annulation |
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| Authors: | Sun-Joon Min Samuel J. Danishefsky |
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| Affiliation: | a Department of Chemistry, Columbia University, 3000 Broadway, New York, NY 10027, USA
b Laboratory for Bioorganic Chemistry, Sloan-Kettering Institute for Cancer Research, 1275 York Avenue, New York, NY 10065, USA |
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| Abstract: | A procedure has been developed for the construction of 7,5-fused ring systems through the ring expansion of silyl enol ethers. This method has been applied to the synthesis of an intermediate en route to the natural product, tricholomalide A. |
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