Facile synthesis of C-decorated Fe,N co-doped TiO2 with enhanced visible-light photocatalytic activity by a novel co-precursor method |
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Authors: | Hualin Jiang Jun Liu Menglin Li Lei Tian Gongsheng Ding Pinghua Chen Xubiao Luo |
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Institution: | 1. Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang 330063, Jiangxi, China;2. College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, Jiangxi, China |
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Abstract: | Lattice-doping and surface decoration are prospective routes to improve the visible-light photocatalytic ability of TiO2, but the two techniques are difficult to combine into one preparation process because they are usually conducted under different conditions, which limits the efficiency of TiO2 modification. In this study, TiO2 was successfully modified by simultaneous lattice-doping and surface decoration, and the visible-light photocatalytic capacity was largely improved. Upon comparing the method reported here with previous ones, the most significant difference is that Fe(II)-phenanthroline was first used as the co-precursor of the introduced elements of C, N, and Fe. These three elements were simultaneously introduced to TiO2 at high levels by this co-precursor method. The as-synthesized photocatalysts were systemically investigated and analyzed by several characterization methods such as XRD, FT-IR, XPS, Raman spectroscopy, EPR, UV-Vis DRS, photoluminescence spectra, photocurrent, electrochemical impedance spectra, TEM, and HRTEM. The photocatalytic degradation of 4-NP under visible-light irradiation was used to evaluate the photocatalytic activity of the photocatalysts. Based on the experimental data, a probable mechanism for the photocatalytic degradation by the photocatalysts is proposed. This is a novel method of using one source to simultaneously introduce metal and non-metal elements to TiO2 at high levels, which may provide a new way to prepare highly effective TiO2 photocatalysts. |
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Keywords: | Lattice doping Surface decoration Photocatalysis 4-nitrophenol removal |
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