Synthesis and Properties of Mononuclear and Homobinuclear Chelates of Mn(II), Co(II), Ni(II), and Cu(II) with Phthalein Purple

Mono- and homobinuclear complexes of Mn(II), Co(II), Ni(II), and Cu(II) with phthalein purple are prepared and characterized by elemental analysis, thermal studies (TGA and DTA), spectral methods (IR, UV/Vis, and ESR), magnetic moment determination, and electrochemical reduction (DC polarography at DME and CV at HMDE). Thermal degradation of the complexes was studied by TGA and DTA where some thermodynamic parameters were determined. The mode of bonding and geometry of the complexes were determined from the spectral studies. Magnetic moment values showed some antiferromagnetism in the homobinuclear complexes. The reduction of the metal ions proceeds to the metallic state along an irreversible process.