Penta- and tetracoordinated phosphorous in reactions of biacetyl with diethylacetylphosphite and diethyl chlorophosphite |
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| Authors: | Ya A Levin I P Gozman S G Salikhov |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry and the Physicotechnological Institute, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions Diethylacetyl phosphite and diethyl chlorophosphite react with biacetyl, intermediately forming, as do other derivatives of phosphorous acid, 1,3,2-dioxaphospholenes with a pentacoordinated phosphorous atom; the latter are rapidly transformed to noncyclic or cyclic derivatives of tetracoordinated phosphorous.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2609–2611, November, 1968.Deceased. |
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