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Two different copper sites in hexakis(1-methyltetrazole)copper(II) bis(tetrafluoroborate) |
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| Authors: | P. E. M. Wijnands W. J. A. Maaskant J. Reedijk |
| Affiliation: | Gorlaeus Laboratories, Department of Chemistry, State University Leyden, P.O Box 9502, 2300 RA Leyden, The Netherlands |
| Abstract: | An electron spin resonance study at temperatures between 300 and 4 K demonstrates that the two crystallographically inequivalent Cu(II) sites in the title compound are subject to different Jahn-Teller behaviour. It is shown that this is not induced by cooperative interactions between the Jahn-Teller sites but arises from the different lattice symmetries of the two sites. |
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