Institution: | a Department of Physics, Faculty of Engineering, Hacettepe University, 06532, Ankara, Turkey b Department of Physics, Faculty of Science and Art, Gazi University, 06500, Ankara, Turkey |
Abstract: | A novel ligand complex of Zn(II) with nicotinamide (one form of niacine) and two bromine ions were synthesised and characterised on the basis of elemental analysis, FT-IR spectroscopy and X-ray crystallography. Crystal system is monoclinic, space group C2/c (no: 15), cell parameters are a=13.3535(9) Å, b=6.3859(7) Å, c=19.1940(19) Å, β=101.75(3)°, V=1602.5(3) Å3 and Z=4. It has been proven that the nicotinamide ligands in the structure of the Zn(II) complex are coordinated to the metal ion with N atoms (ZnBr2(na)2] where na: nicotinamide). |