摘 要: | The stability constants of the binary complexes ofCu~(2+) with isoquinoline and benzimidazole as well as the ternarycomplexes of Cu(ATP)with the same ligands have been measuredin aqueous solution spectrophotometrically and a strongstacking interaction between the heteroaromatic ring of theligands and the purine moiety of ATP has been found.The factof this stacking interaction is much stronger than that in thesystems of Cu(ATP)with pyridine and imidazole shows thatthe stacking interaction increases with the size of theheteroaromatic ring of the ligands.
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