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Interpenetrating polymer networks based on diisocyanates and polar monomers
Authors:GP Belonovskaya  JD Chernova  LA Korotneva  LS Andrianova  BA Dolgoplosk  SK Zakharov  YuN Sazanov  KK Kalninsh  LM Kaliuzhnaya  MF Lebedeva
Institution:Institute of Macromolecular Compounds, Academy of Sciences of U.S.S.R. Leningrad, U.S.S.R.
Abstract:Compatible interpenetrating polymer networks systems (IPS) have been obtained by two-stage polymerization of a mixture of diisocyanates (M1) with various different polar monomers (M2) initiated by catalytic systems based on tertiary amines. In the first stage, a polyisocyanate network (P1) is formed and then M2 is polymerized on a regenerated active centre with the formation of a linear polymer (L2) specially arranged in P1. The essential features of the formation of IPS of this type are considered. Some physico-mechanical and thermal characteristics are reported.
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