Telomerization of vinyl chloride by benzyl chloride |
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| Authors: | T. T. Vasil'eva V. I. Dostovalova R. Kh. Freidlina |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The systems Fe(CO)5 + hexamethylphosphotriamide and Fe(CO)5 + DMF are efficient initiators for the telomerization of vinyl chloride by benzyl chloride involving the C-Cl bond of the benzyl chloride, in which connection both the conversion of the telogen and yield of telomers is high. Telomers of general formula C6H5CH2-(CH2CHCl)nCl (n=1–3) were isolated.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2541–2546, November, 1980. |
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