A versatile and modular approach to functionalisation of deep-cavity cavitands via"click" chemistry |
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Authors: | Li Yejia Giles Marco D Liu Simin Laurent Boyd A Hoskins Jessica N Cortez Mallory A Sreerama Subramanya G Gibb Bruce C Grayson Scott M |
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Institution: | Department of Chemistry, Tulane University, New Orleans, LA 70118, USA. |
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Abstract: | The surface modification of deep-cavity cavitands has been demonstrated by using the azide-alkyne "click" coupling to attach dendritic macromolecules or linear polymers onto their periphery. The resulting set of macromolecular cavitands exhibited tuneable solubility yet retained the ability to encapsulate guest molecules. |
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