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A versatile and modular approach to functionalisation of deep-cavity cavitands via"click" chemistry
Authors:Li Yejia  Giles Marco D  Liu Simin  Laurent Boyd A  Hoskins Jessica N  Cortez Mallory A  Sreerama Subramanya G  Gibb Bruce C  Grayson Scott M
Institution:Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Abstract:The surface modification of deep-cavity cavitands has been demonstrated by using the azide-alkyne "click" coupling to attach dendritic macromolecules or linear polymers onto their periphery. The resulting set of macromolecular cavitands exhibited tuneable solubility yet retained the ability to encapsulate guest molecules.
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