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A linear single-molecule magnet based on [Ru(III)(CN)6]3-
Authors:Pedersen Kasper S  Dreiser Jan  Nehrkorn Joscha  Gysler Maren  Schau-Magnussen Magnus  Schnegg Alexander  Holldack Karsten  Bittl Robert  Piligkos Stergios  Weihe Høgni  Tregenna-Piggott Philip  Waldmann Oliver  Bendix Jesper
Affiliation:Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark. ksp@kiku.dk bendix@kiku.dk
Abstract:We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru(III)(CN)(6)](3-). Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.
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