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Investigation of the Crystallization Kinetics of Zn(Leu)SO4·0.5H2O in Mixing Solvent by Microcalorimetry
Authors:Chen San‐Ping  Fang Yan  Gao Sheng‐Li  Hu Rong‐Zu
Abstract:The crystal growth process of Zn(Len)SO4·0.5H2O from water and acetone was investigated using a Calvet microcalorimeter. The heat and the rate of heat production during the crystal growth process at 293.15 K, 295.15 K, 298.15 K and 300.15 K were measured. On the basis of experimental and calculated results, the rate constant and the kinetic parameters (the activation energies, the pre‐exponential) during the crystal growth process were obtained. The results show that the crystal growth process accorded with the Burton‐Cabrera‐Frank dislocation theory.
Keywords:zinc sulfate  L‐a‐leucine  complex  crystallization kinetics  microcalorimetry
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