An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide |
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Authors: | Kishali Nurhan Horasan Sahin Ertan Kara Yunus |
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Institution: | Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240 Erzurum, Turkey. nhorasan@atauni.edu.tr |
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Abstract: | reaction: see text] A new and stereospecific synthesis for bis-endoperoxide has been developed starting from tetrahydronaphthalene. Photooxygenation of tetrahydronaphthalene resulted in the formation of hydroperoxy-endoperoxide. The bromination reaction of hydroperoxy-endoperoxide gave bis-endoperoxide, whose exact configuration has been determined by X-ray analysis. The lowest-energy conformer of bis-endoperoxide is the boat-chair form. |
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