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Stacked platinum complexes of the magnus' salt type inside a coordination cage |
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| Authors: | Clever Guido H Kawamura Wataru Tashiro Shohei Shiro Motoo Shionoya Mitsuhiko |
| Affiliation: | 1. Institute for Inorganic Chemistry, Georg‐August University, G?ttingen, Tammannstr. 4, 37077 G?ttingen (Germany);2. Department of Chemistry, Graduate School of Science, The University of Tokyo, 7‐3‐1 Hongo, Bunkyo‐ku, Tokyo 113‐0033 (Japan);3. Rigaku Co. LTD (Japan) |
| Abstract: | Neatly wrapped up: alternately stacked square-planar platinum(II) complexes inside a dinuclear coordination cage were prepared to give a discrete and soluble Pt(5) -array of the Magnus' salt type. Characterization of the complex in solution was complemented by an X-ray crystal structure of {[Pt(pyridine)(4)]? [PtCl(4)](2) @Cage}; this structure showed the linear, pentanuclear array within the cages and their circular packing into a hollow tubular superstructure. |
| Keywords: | cage compounds host–guest systems metal stacking platinum supramolecular chemistry |
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